Product ID:SULFURIC-PHOSPHORIC ACID MIXTURE
MSDS Date:03/10/1989
FSC:6810
NIIN:00N039817
MSDS Number: BRPNN

RED BIRD SERVICE

205 WESTERN AVE
OSGOOD, IN 47037
US

Emergency Phone: 812-689-4040;800-428-3502

Info Phone: 812-689-4040;800-428-3502

Preparer: GENE C. FEITH

Cage: 0H0Z7

RED BIRD SERVICE

OSGOOD, IN 47037 US

Telephone: 812-689-4040;800-428-3502

Cage: 0H0Z7

ALSO A DEHYDRATING AGENT, PICKING UP MOISTURE

RTECS: 9999999ZZ

W/LRG AMTS OF MILK OR WATER, THEN GIVE MILK

RTECS: 9999999ZZ

IT OCCURS SPONTANEOUSLY, CONTINUE TO GIVE FLUID. GET

RTECS: 9999999ZZ

AN UNCONSCIOUS PERSON. MAINTAIN OBSERVATION OF

RTECS: 9999999ZZ

POSE A SPECIAL HAZ; SOFT LENSES ABSORB & ALL LENSES

RTECS: 9999999ZZ

LIME. MAJOR SPILLS MUST BE HANDLED BY A

RTECS: 9999999ZZ

PLANNING & TO MEET REQUIREMENTS & DISPOSING OF LARGE

RTECS: 9999999ZZ

ACID. COMPREHENSIVE PREPLACEMENT & ANNUAL

RTECS: 9999999ZZ

MEMBRANE IRRITATION AND COUGH. GLASS BOTTLES NEED

RTECS: 9999999ZZ

MOST METALS ESPECIALLY BELOW 77% H*2*SO*4. DO NOT

RTECS: 9999999ZZ

(ORAL RAT) 2140 MG/KG.

CAS: 7664-93-9

RTECS: WS5600000

Fraction By Weight: 50%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

(ORAL RAT) 1530 MG/KG.

CAS: 7664-38-2

RTECS: TB6300000

Fraction By Weight: 50%

OSHA PEL 1 MG/M3;3 STEL

ACGIH TLV: 1 MG/M3;3 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CONCENTRATED SULFURIC ACID IS A STRONG
MINERAL ACID, AN OXIDIZING AGENT, AND A DEHYDRATING AGENT THAT IS
RAPIDLY DAMAGING TO ALL HUMAN TISSUE WITH WHICH IT COMES IN
CONTACT. INGESTION MAY CAUSE SEVERE INJURY OR DEATH. EYE CONTACT
CAUSES SEVERE OR PERMANENT INJURY. INHALATION OF MISTS CAN DAMAGE
BOTH (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:THE UPPER RESPIRATORY TRACT AND LUNGS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE:IMMED FLUSH W/PLENTY OF RUNNING WATER FOR AT LEAST 15
MINS INCL UNDER EYELIDS. SPEED IN DILUTING & RINSING OUT ACID
W/WATER IS EXTREMELY IMPORTANT IF PERM EYE DMG IS TO BE AVOIDED.
GET MD AS SOON AS POSS. SKIN:IMMED FLUSH W/WATER, REMOVING CONTAM
CLTHG UNDER SAFETY SHOWER. CONTINUE WASHING W/WATER & GET MD.
INHAL:MOVE TO FRESH AIR. RESTORE BRTHG. CALL MD IMMED.
INGEST:DILUTE ACID IMMED(ING 4)

Flash Point:NON FLAMMABLE
Extinguishing Media:FIRES INVOLVING SMALL AMTS MAY BE SMOTHERED
W/SUITABLE DRY CHEM. USE WATER ON COMBUSTS BURNING IN VICINITY OF
(SUPDAT)
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . SULFURIC ACID MISTS & VAPS FROM FIRE AREA
ARE CORROSIVE. THIS IS A VERY POWERFUL (SUPP DATA)
Unusual Fire/Explosion Hazard:EVEN THOUGH SULFURIC ACID IS
NONFLAMMABLE, IT IS HAZARDOUS WHEN PRESENT IN FIRE AREA. DO NOT ADD
WATER OF OTHER FLUID TO ACID. THE ACID, ESPECIALLY WHEN(SUPDAT)

Spill Release Procedures:PVNT CNTCT W/ACID. PROVIDE ADEQ VENT TO CNTRL
WORKPLACE CONC. MINOR LEAKS OR SPILLS CAN BE DILUTED W/PLENTY OF
WATER & NEUTRALIZED W/SODA ASH OR LIME. IF WATER IS NOT AVAIL,
COVER CONTAM AREA W/SAND, ASHES OR GRAVEL & NEUTRALIZE W/SODA
ASHOR (ING 8)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP OUT OF DIRECT SUNLIGHT, DO NOT
STORE ABOVE 32C. PROTECT CONTAINERS FROM PHYSICAL DAMAGE.
Other Precautions:STORAGE FACILITIES TO BE SEPARATE FROM METALLIC
POWDERS, CHROMATES, CHLORATES, NITRATES, CARBIDES, OXIDIZABLES,
ETC. SODA ASH OR LIME SHOULD BE KEPT IN GENERAL STORAGE OR WORK
AREAS FOR EMERG USE. DO NOT ADD WATER TO CONC SULFURIC (ING 10)

Respiratory Protection:ALL RESPIRATORS MUST BE NIOSH/MSHA APPROVED.
WHERE MISTS ARE UP TO 50 MG/M3, HIGH EFFICIENCY PARTICULATE
RESPIRATOR W/FULL FACEPIECE IS WARRANTED; TYPE C SUPPLIED AIR RESP
W/FULL FACEPIECE OPERATED IN PRESS DEMAND MODE IS USE TO 100
MG/M3.
Ventilation:PROVIDE GENERAL VENTILATION TO MEET CURRENT TLV
REQUIREMENTS IN THE WORKPLACE.
Protective Gloves:RUBBER GLOVES.
Eye Protection:CHEM WORK GOGG/FULL LENGTH FSHLD .
Other Protective Equipment:IMPERVIOUS PROTECTIVE CLOTHING (APRONS,
BOOTS & SUITS) ARE RECOMMENDED. EYE WASH FOUNTAINS & SAFETY
SHOWERS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXTING MEDIA:MATL. WATER ADDED TO MATL CAN PRODUCE HEAT & SPATTERING.
USE CAUTION. FIRE FIGHT PROC:ACIDIC OXIDIZER WHICH CAN IGNITE OR
EVEN EXPLODE ON CNTCT W/MANY MATLS. EXPLO HAZ:DILUTED W/WATER, CA N
REACT W/METALS TO LIBERATE FLAMM HYDROGEN GAS. MATLS TO AVOID:IGNIT
OF COMBUST MATLS ON CNTCT. CONC ACID IS (ING 3)

Boiling Pt:B.P. Text:327F,164C
Vapor Pres:3
Vapor Density:0.7
Spec Gravity:1.77 (H*2O=1)
Evaporation Rate & Reference:>1 (BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:A CLEAR, COLORLESS HYGROSCOPIC OILY LIQUID WITH NO
ODOR
Percent Volatiles by Volume:NONE

Stability Indicator/Materials to Avoid:YES
IT IS A STRONG MINERAL ACID REACTIONG W/BASES & METALS. THE CONC ACID
IS A STRONG OXIDIZING AGENT & CAN CAUSE (SUPDAT)
Stability Condition to Avoid:REACTS EXOTHERMICALLY W/WATER. SULFUR
OXIDES CAN RESULT FROM DECOMPOSITION & FROM OXIDIZING REACTIONS OF
SULFURIC ACID.
Hazardous Decomposition Products:POSSIBLE FUMES OF SO*X AND PO*X.

Waste Disposal Methods:FOLLOW ALL FEDERAL, STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.